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Nanomaterials with laser printing

Catalysts which generate hydrogen and other substances can be produced more efficiently

An interdisciplinary team from the Max Planck Institute of Colloids and Interfaces presents a laser-driven technology that enables them to create nanoparticles out of materials such as copper, cobalt and nickel oxides. At the usual printing speed, photoelectrodes are produced in this way, for example, for a wide range of applications such as the generation of green hydrogen.

Previous methods produce such nanomaterials only with high energy input in classical reaction vessels and in many hours. With the laser-driven technology developed at the institute, the scientists can deposit small amounts of material on a surface and simultaneously perform chemical synthesis in a very short time using high temperatures from the laser. ‘When I discovered the nanocrystals under the electron microscope, I knew I was onto something big,’ says Junfang Zhang, first author of the study and doctoral researcher. The discovery turned into a new and environmentally friendly method for synthesizing materials that can, among other things, use solar energy for chemical reaction such as the formation hydrogen.

Without detours with sunlight to hydrogen
‘Nowadays most of green hydrogen is produced from water using electricity generated by solar panels and stored in batteries. By employing photoelectrodes we can use solar light directly,’ says Aleksandr Savateev. The newly developed principle works with so-called transition metal oxides, mainly copper, cobalt and nickel oxides, all of which are good catalysts. The special feature of these oxides is the variety of their crystal forms (nanocrystals such as nanorods or nanostars), which affect their surface energy. Each structure can have a different effect on catalytic reactions. Therefore, it is important that these nanostructures can be made targeted - or even untargeted, but repeatable. The developed technology could also be used to find quickly and efficiently new catalysts. ‘Laser dot by laser dot, we can create different catalysts side by side by simply varying the composition and conditions, and then also test them in parallel right away,’ says Dr. Felix Löffler adding, ‘But now we need to work on making the catalyst systems more persistent in all applications’.

Similar to the principle of a typewriter, material is transferred from a donor to an acceptor carrier. On the former is the ‘ink’, a solid polymer, which is mixed with metal salts, the latter consists of a thin carbon nitride film on a conductive electrode. Targeted laser irradiation transfers the salts to the acceptor along with the molten polymer. The brief high temperatures cause the salts to react within milliseconds and they transform into metal oxide nanoparticles with desired morphology.”

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