“Perovskite solar cells have been attracting great attention from the scientific and industrial communities in the past few years because they are able to combine high power conversion efficiencies under standard test conditions (i.e. those of the sun) with simple manufacturing processes. The films that make up the cells are in fact cast from solution (i.e. printed via inks) or evaporated over large areas.
Franco Cacialli, Professor of Physics in the London Centre for Nanotechnology and the Department of Physics and Astronomy at UCL, in collaboration with researchers at the Centre for Hybrid and Organic Solar Energy (CHOSE), Department of Electronic Engineering University of Rome – Tor Vergata, have developed perovskite solar cells with maximum power density under white LED illumination of 20.2 µW/cm2 at 200 1x and 41.6 µW/cm2 at 400 1x (corresponding to a power conversion of 27%).
The authors of the work believe these to be the highest power output densities ever reported under illumination conditions typically found in homes and offices. The exceptional performance under indoor lighting was achieved by incorporating new solution-processed SnO2/MgO composite electron transport layers between the perovskite semiconductor film and the bottom transparent electrode. The thin MgO overlayer enhances efficiency by roughly 20%, reducing charge recombination which is especially important at the low light levels typically found indoors. Results have recently been published in Nano Energy.
All layers of the cells, except for the two electrodes, were solution processed at low temperatures, making the technology easy to integrate with other printed electronic components on the same substrate, and compatible with low cost manufacturing. Ambient indoor conditions represent a milder environment compared to stringent outdoor conditions suggesting an initial commercial outlet which is much less taxing on device lifetimes for this technology. Thus, the researchers suggest that the unparalleled performance demonstrated, furnishes these devices with another new powerful competitive attribute that can pave the way for perovskite solar cells to contribute strongly to energy harvesting and the powering of the indoor electronics of the future (e.g. the fast-rising markets of autonomous indoor wireless sensor networks and the internet of things).
The results have been published in Nano Energy: “Highly efficient perovskite solar cells for light harvesting under indoor illumination via solution processed SnO2/MgO composite electron transport layers”, Janardan Dagar, Sergio Castro-Hermosa, Giulia Lucarelli. Franco Cacialli, Thomas M. Brown.”